全文获取类型
收费全文 | 145250篇 |
免费 | 21012篇 |
国内免费 | 15123篇 |
专业分类
电工技术 | 12678篇 |
技术理论 | 9篇 |
综合类 | 18895篇 |
化学工业 | 11795篇 |
金属工艺 | 4871篇 |
机械仪表 | 10522篇 |
建筑科学 | 13967篇 |
矿业工程 | 5429篇 |
能源动力 | 6532篇 |
轻工业 | 4595篇 |
水利工程 | 9137篇 |
石油天然气 | 9416篇 |
武器工业 | 2198篇 |
无线电 | 11841篇 |
一般工业技术 | 12475篇 |
冶金工业 | 5078篇 |
原子能技术 | 1369篇 |
自动化技术 | 40578篇 |
出版年
2024年 | 388篇 |
2023年 | 2413篇 |
2022年 | 4600篇 |
2021年 | 5410篇 |
2020年 | 5643篇 |
2019年 | 4854篇 |
2018年 | 4546篇 |
2017年 | 5565篇 |
2016年 | 6455篇 |
2015年 | 6762篇 |
2014年 | 9083篇 |
2013年 | 9479篇 |
2012年 | 10800篇 |
2011年 | 11653篇 |
2010年 | 9107篇 |
2009年 | 9435篇 |
2008年 | 9425篇 |
2007年 | 10617篇 |
2006年 | 9233篇 |
2005年 | 8073篇 |
2004年 | 6559篇 |
2003年 | 5711篇 |
2002年 | 4504篇 |
2001年 | 3751篇 |
2000年 | 3146篇 |
1999年 | 2445篇 |
1998年 | 2032篇 |
1997年 | 1692篇 |
1996年 | 1562篇 |
1995年 | 1394篇 |
1994年 | 1143篇 |
1993年 | 797篇 |
1992年 | 670篇 |
1991年 | 531篇 |
1990年 | 417篇 |
1989年 | 356篇 |
1988年 | 222篇 |
1987年 | 136篇 |
1986年 | 110篇 |
1985年 | 107篇 |
1984年 | 108篇 |
1983年 | 62篇 |
1982年 | 79篇 |
1981年 | 47篇 |
1980年 | 56篇 |
1979年 | 54篇 |
1978年 | 19篇 |
1962年 | 10篇 |
1959年 | 20篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
《岩石力学与岩土工程学报(英文版)》2022,14(5):1626-1641
Understanding the spatiotemporal evolution of overburden deformation during coal mining is still a challenge in engineering practice due to the limitation of monitoring techniques. Taking the Yangliu Coal Mine as an example, a similarity model test was designed and conducted to investigate the deformation and failure mechanism of overlying rocks in this study. Distributed fiber optic sensing (DFOS), high-density electrical resistivity tomography (HD-ERT) and close-range photogrammetry (CRP) technologies were used in the test for comprehensive analyses. The combined use of the three methods facilitates the investigation of the spatiotemporal evolution characteristics of overburden deformation, showing that the mining-induced deformation of overburden strata was a dynamic evolution process. This process was accompanied by the formation, propagation, closure and redevelopment of separation cracks. Moreover, the key rock stratum with high strength and high-quality lithology played a crucial role in the whole process of overburden deformation. There were generally three failure modes of overburden rock layers, including bending and tension, overall shearing, and shearing and sliding. Shear failure often leads to overburden falling off in blocks, which poses a serious threat to mining safety. Therefore, real-time and accurate monitoring of overburden deformation is of great significance for the safe mining of underground coal seams. 相似文献
52.
53.
《Advanced Powder Technology》2022,33(8):103637
With excellent micromixing characteristic of rotating packed bed (RPB), many nanoparticles with small average size, narrower distribution and good morphology had been successfully and continuously prepared. To reveal complex crystal process, an empirical model were developed to simulate nano-ZnO by considering mass changed, population balance equation, growth rate G, nucleation rate B, drop sizes Di, and resident time t. The predicted particle sizes were shown good agreement with experimental data with error of ±10%. Therefore, it was further adopted to predict the effects of rotating speed, liquid flow rate and reactant concentration on the mean particle size. To look more deeply insight in this process, their contribution ratios were further analyzed. The proposed empirical models were of great helpful to obtain suitable operation conditions for preparing much better properties of nanoparticles with fewer experiments. It was also beneficial to produce other nanoparticles in RPB. 相似文献
54.
《International Journal of Hydrogen Energy》2022,47(57):24242-24253
As hydrogen refueling stations become increasingly common, it is clear that a high level of economic efficiency and safety is crucial to promoting their use. One way to reduce costs is to use a simple orifice instead of an excess flow valve, which Japanese safety regulations have identified as a safety device. However, there is concern about its effect on refueling time and on risk due to hydrogen leakage. To clarify the effect, we did a study of model-based refueling time evaluation and quantitative risk assessment for a typical refueling station. This study showed that an orifice is an effective alternative safety device. The increase in refueling time was less than 10%, based on simulations using a dynamic physical model of the station. Neither was there a significant difference in the risk between a configuration with excess flow valves and one with an orifice. 相似文献
55.
《International Journal of Hydrogen Energy》2022,47(75):32031-32038
The activity of catalysts with various sizes was compared in a fixed-bed Fischer–Tropsch reactor under similar operating conditions by determining the deactivation model. Catalyst size had no impact on the type of deactivation model. The smaller catalyst showed a smaller deactivation constant of catalyst (kd) and a lower deactivation rate in the initial stage. The decline in the activities of the catalyst with a mesh size of 40 was lower than the other catalysts, suggesting its higher long-term stability (ass). Larger catalyst sizes led to the fouling of carbon and heavy hydrocarbons, decreasing the specific surface of the catalyst, thus increasing the pore diffusion resistance and further decrementing the catalyst activities. 相似文献
56.
《International Journal of Hydrogen Energy》2022,47(91):38884-38894
This paper presents experiments performed at Canadian Nuclear Laboratories (CNL) to examine the dispersion behaviour of helium in a polycarbonate enclosure that was representative of a residential parking garage. The purpose was to gain a better understanding of the effect of buoyancy- or wind-driven natural ventilation on hydrogen dispersion behaviour. Although hydrogen dispersion studies have been reported extensively in the literature, gaps still exist in predictive methods for hazard analysis. Helium, a simulant for hydrogen, was injected near the centre of the floor with a flow rate ranging from 5 to 75 standard litres per minute through an upward-facing nozzle, resulting in an injection Richardson number ranging between 10?1 and 102. The location of the nozzle varied from the bottom of the enclosure to near the ceiling to examine the impact of the nozzle elevation on the development of a stratified layer in the upper region of the enclosure. When the injection nozzle was placed at a sufficiently low elevation, the vertical helium profile always consisted of a homogenous layer at the top overlaying a stratified layer at the bottom. To simulate outdoor environmental conditions, a fan was placed in front of each vent to examine the effect of opposing or assisting wind on the dispersion. The helium transients in the uniform layer predicted with analytical models were in good agreement with the measured transients for most tests. Model improvements are required for adequately predicting transients with primarily stratified profiles or strong opposing wind. 相似文献
57.
《International Journal of Hydrogen Energy》2022,47(91):38721-38735
Proper management of the liquid water and heat produced in proton exchange membrane (PEM) fuel cells remains crucial to increase both its performance and durability. In this study, a two-phase flow and multicomponent model, called two-fluid model, is developed in the commercial COMSOL Multiphysics® software to investigate the liquid water heterogeneities in large area PEM fuel cells, considering the real flow fields in the bipolar plate. A macroscopic pseudo-3D multi-layers approach has been chosen and generalized Darcy's relation is used both in the membrane-electrode assembly (MEA) and in the channel. The model considers two-phase flow and gas convection and diffusion coupled with electrochemistry and water transport through the membrane. The numerical results are compared to one-fluid model results and liquid water measurements obtained by neutron imaging for several operating conditions. Finally, according to the good agreement between the two-fluid and experimentation results, the numerical water distribution is examined in each component of the cell, exhibiting very heterogeneous water thickness over the cell surface. 相似文献
58.
《International Journal of Hydrogen Energy》2022,47(3):2040-2049
The motion trajectory of hydrogen leakage is an essential safe issue for the application of hydrogen energy. A dimensionless fast-running motion trajectory prediction model is proposed to predict the dispersion characteristics of the buoyant jet of hydrogen leakage for the accident. The impact of different leakage angles, leakage velocity and thermal stratification of ambient air on hydrogen leakage behavior was analyzed. The new developed model was verified by experimental results in literatures. Leakage hydrogen can flow upwards freely in a uniform environment. However, it shows an oscillating trajectory at a certain height in a thermally stratified environment, which is so called “locking phenomenon”. The trajectory of hydrogen leakage is upward and hydrogen gathers at the top of the space to form stratification in a uniform environment, while the hydrogen leakage shows an oscillating trajectory at a certain height in a thermal stratification environment. With the increase of Froude number Fr, it shows that the stable height and maximum height of the leakage airflow have a trend of rising first and then falling in a thermally stratified environment. The findings are expected to give guidance in real-world situations, for example, a larger Fr value and a larger temperature gradient can lead to a decrease in the stable height in the thermally stratified environment. It is found that the fitting of the stable height with different temperature gradients satisfies the power function relationship. This work is expected to be helpful for reducing hydrogen leakage accumulation and explosion risk. 相似文献
59.
《International Journal of Hydrogen Energy》2022,47(10):6494-6507
The Markov model and the PEM electrolyzer system model for directly coupled photovoltaic are combined to construct an efficient and reliable working condition that fits the fluctuation characteristics of solar energy. The working condition is designed through genetic algorithm so that the average coupling efficiency of the system can reach 98.8%. Then, the durability and recovery test are conducted on the basis of the constructed conditions. It is found that the attenuation rate at the current density of 1A/cm2 under the photovoltaic fluctuating condition reached 7.8mV/h, which is twice that under the constant current condition. The charge transfer impedance (Rct) is the main factor leading to the degradation. It is proved by the recovery experiment that the increase of Rct is related to the pollution of metal ions. After pickling to remove some metal ions, Rct can be significantly reduced by 46.8% and 65.2%, respectively. After the durability test, the voltammetric charges under the photovoltaic fluctuating condition and the constant current condition are reduced by 48.3% and 19.1% It indicates that the photovoltaic fluctuation condition will accelerate the attenuation of the effective reaction area of MEA, which is irreversible even after pickling. It can be observed from the SEM images that the catalyst layer of MEA has more obvious peeling under the photovoltaic fluctuation condition, which is not conducive to material transmission and destroys the transmission channel of ions and electrons. This result can provide a reliable reference for the coupling design of PEM electrolyzer and renewable energy in the future. 相似文献
60.
《International Journal of Hydrogen Energy》2022,47(19):10777-10787
In this work, a practical numerical model with few parameters was proposed for the prediction of environmental hydrogen embrittlement. The proposed method adopts hydrogen enhanced plasticity-based mechanism in a fracture strain model to describe hydrogen embrittlement. Fracture toughness degradation of three commercial steels SA372J70, AISI4130 and X80 in high pressure hydrogen environment were investigated. Firstly, governing equations for hydrogen distribution and material damage evolution was established. Hydrogen enhanced localized flow softening effect was coupled within fracture strain dependency on stress triaxiality. Then, the numerical implementation and identification process of model parameters was described. Model parameters of the investigated steels were determined based on experiment results from literatures. Finally, with the calibrated model, fracture toughness reduction of the steels was predicted in a wide range of hydrogen pressure. The prediction results were compared with experimental results. Reasonable accuracy was reached. The proposed method is an attempt to reach balance between physical accurate prediction and engineering practicality. It is promising to provide a simplified numerical tool for the design and fit for service evaluation of hydrogen storage vessels. 相似文献